Inherent structure entropy of supercooled liquids

Citation
F. Sciortino et al., Inherent structure entropy of supercooled liquids, PHYS REV L, 83(16), 1999, pp. 3214-3217
Citations number
45
Categorie Soggetti
Physics
Journal title
PHYSICAL REVIEW LETTERS
ISSN journal
00319007 → ACNP
Volume
83
Issue
16
Year of publication
1999
Pages
3214 - 3217
Database
ISI
SICI code
0031-9007(19991018)83:16<3214:ISEOSL>2.0.ZU;2-Y
Abstract
We present a quantitative description of the thermodynamics in a supercoole d binary Lennard-Jones liquid via the evaluation of the degeneracy of the i nherent structures, i.e., of the number of potential energy basins in confi guration space. We find that the contribution of the inherent structures to the free energy of the liquid almost completely decouples from the vibrati onal contribution. An important by-product of the presented analysis is the determination of the Kauzmann temperature for the studied system.