Low temperature scanning tunneling microscopy (STM) has been used to identi
fy the molecular orientation of individual C-60 on Si(111)-(7 X 7) surfaces
. The STM images of individual C-60 reveal clear and rich intramolecular fe
atures that are site and bias dependent. Theoretical simulations, using the
local density approximation method with cluster models, uniquely reproduce
the observed STM images and hence allow the unambiguous identification of
the binding configurations of the adsorbed fullerenes with respect to the S
i substrate.