HIGHLY REGIOSELECTIVE ALLYLIC SUBSTITUTION MEDIATED BY CHIRAL RHENIUMCOMPLEXES

Authors
LEGOUPY S CREVISY C GUILLEMIN JC GREE R
Citation
S. Legoupy et al., HIGHLY REGIOSELECTIVE ALLYLIC SUBSTITUTION MEDIATED BY CHIRAL RHENIUMCOMPLEXES, Organometallics, 16(9), 1997, pp. 1822-1824
Citations number
25
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
9
Year of publication
1997
Pages
1822 - 1824
Database
ISI
SICI code
0276-7333(1997)16:9<1822:HRASMB>2.0.ZU;2-I
Abstract
The nucleophilic addition of alcohols, thiols, allylsilane, or triphen ylphosphine on an allylic alcohol complexed to a chiral rhenium salt l eads, in the presence of an acid, to the corresponding ethers, thioeth ers, 1,5-diene, and phosphonium salt in high yields. The high regiosel ectivity of these reactions is unambiguously established using a deute rated ligand.