Zwitterionic copper(I) pi-complexes: Synthesis and crystal structure of [(CH2 = CH-CH2)(2)NH2]Cu2Cl3

Authors
Oliinik, VV Glovyak, T Mys'kiv, MG
Citation
Vv. Oliinik et al., Zwitterionic copper(I) pi-complexes: Synthesis and crystal structure of [(CH2 = CH-CH2)(2)NH2]Cu2Cl3, RUSS J C CH, 25(10), 1999, pp. 738-743
Citations number
6
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
RUSSIAN JOURNAL OF COORDINATION CHEMISTRY
ISSN journal
10703284 → ACNP
Volume
25
Issue
10
Year of publication
1999
Pages
738 - 743
Database
ISI
SICI code
1070-3284(199910)25:10<738:ZCPSAC>2.0.ZU;2-O
Abstract
Crystals of novel olefinic pi-complex [(CH2=CH-CH2)(2)NH2]Cu2Cl3 (I) were p repared by the ne electrochemical method. It was found (single-crystal KM-4 X-ray diffractometer, MoKalpha radiation, omega/2 theta scan mode) that I [space group P (1) over bar, a = 7.210(1), b = 7.4339(9), c = 10.093(2) Ang strom, alpha = 95.63(1)degrees, beta = 107.90(2)degrees, gamma = 91.95(1)de grees] is not isostructural with the previously studied [(CH2=CH-CH2)(2)NH2 ]Cu2Br3.