Determination of hydrogen solubility in oxide ceramics by using SIMS analyses

Authors
Sakai, N Yamaji, K Horita, T Yokokawa, H Hirata, Y Sameshima, S Nigara, Y Mizusaki, J
Citation
N. Sakai et al., Determination of hydrogen solubility in oxide ceramics by using SIMS analyses, SOL ST ION, 125(1-4), 1999, pp. 325-331
Citations number
13
Categorie Soggetti
Apllied Physucs/Condensed Matter/Materiales Science
Journal title
SOLID STATE IONICS
ISSN journal
01672738 → ACNP
Volume
125
Issue
1-4
Year of publication
1999
Pages
325 - 331
Database
ISI
SICI code
0167-2738(199910)125:1-4<325:DOHSIO>2.0.ZU;2-6
Abstract
Hydrogen solubility in oxide ceramics was evaluated by annealing in D2O-con taining atmosphere and subsequent secondary ion mass spectrometry (SIMS). A good proportional relation was obtained between the relative intensity of deuterium ion in SIMS and literature data of hydrogen solubility for YSZ an d Sr(Yb)CeO3-delta. The hydrogen solubility in CeO2 and rare-earth doped ce ria (Ce0.8M0.2O1.9, M = Y, La, Nd, Sm, Gd, Yb) was evaluated. The hydrogen solubility in ceria dramatically increased by rare earth substitution, and it depended on the lattice parameter of Ce0.8M0.2O1.9. (C) 1999 Elsevier Sc ience B.V. All rights reserved.