One-pot synthesis of some 3-silylprop-2-enyl phosphine oxides and -diethylphosphonates

Authors
Gawdzik, B Wawrzenczyk, C
Citation
B. Gawdzik et C. Wawrzenczyk, One-pot synthesis of some 3-silylprop-2-enyl phosphine oxides and -diethylphosphonates, SYNTHESIS-S, (10), 1999, pp. 1759-1762
Citations number
11
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
SYNTHESIS-STUTTGART
ISSN journal
00397881 → ACNP
Issue
10
Year of publication
1999
Pages
1759 - 1762
Database
ISI
SICI code
0039-7881(199910):10<1759:OSOS3P>2.0.ZU;2-T
Abstract
An efficient and facile method for the synthesis of 3(alkyldimethylsilylpro p-2-en-1-yl)diphenylphosphine oxides and diethyl 3-(alkyldimethylsilylprop- 2-en-1-yl)phosphonates with alkyl (methyl or butyl), alkenyl (allyl or viny l) and ethynyl group at silicon is presented. An example of application of these synthons in the synthesis of dienyl silanes is given.