The adsorption of pentachlorophenol (PCP) on a soil was studied by equilibr
ating the soil (with and without its indigenous organic matter) with PCP in
the presence and the absence of added natural organic species (benzoic aci
d, lactic acid, glucuronic acid and catechol). Both the added organic speci
es and the indigenous organic matter were found to enhance PCP adsorption,
the enhancement being greater with benzoic acid than with the less hydropho
bic lactic acid. Adsorption of these organic species was also enhanced by P
CP, suggesting the existence of a co-operative adsorption mechanism.