Resonance Raman evidence for the interconversion between an [Fe-III-eta(1)-OOH] (2+) and [Fe-III-eta(2)-O-2](+) species and mechanistic implications thereof

Authors
Ho, RYN Roelfes, G Hermant, R Hage, R Feringa, BL Que, L
Citation
Ryn. Ho et al., Resonance Raman evidence for the interconversion between an [Fe-III-eta(1)-OOH] (2+) and [Fe-III-eta(2)-O-2](+) species and mechanistic implications thereof, CHEM COMMUN, (21), 1999, pp. 2161-2162
Citations number
22
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
21
Year of publication
1999
Pages
2161 - 2162
Database
ISI
SICI code
1359-7345(1999):21<2161:RREFTI>2.0.ZU;2-5
Abstract
The deprotonation of [Fe-III(N4Py)(eta(1)-OOH)](2+) 1 gives [Fe-III(N4Py)(e ta(2)-OO)](+) 2, as unequivocally demonstrated by resonance Raman spectrosc opy, and leads to the loss of alkane hydroxylation activity by 1.