Oj. Kjonaas, Factors affecting stability and efficiency of ion exchange resins in studies of soil nitrogen transformation, COMM SOIL S, 30(17-18), 1999, pp. 2377-2397
Mixtures of cation and anion exchange resins are used as part of the resin
core technique to determine nitrogen transformation in forest soils as they
adsorb the NH4-N and NO3-N from soil solution percolating through the incu
bated soil cores. In the field, the exchange resins may be subjected to a v
ariety of conditions, involving drying, rehydration, freezing, and thawing.
This paper examines how these processes affect adsorption of NH4-N and NO3
-N and the stability of the resins. Lab tests were performed on the anion r
esin Amberlite IRA-93, the cation resin Amberlite IR-120, a mixture of IRA-
93 and IR-120, and the commercially-mixed bed resin Amberlite MB 1. The bac
kground content of NO3-N and NH4-N on the resins was large and highly varia
ble between different batches of resins in spite of a 2 M NaCI pre-rinse. T
he IR-120 cation resin that was subjected to 48 hours air-drying contained
significantly less NH4-N than the moist resins, while the drying of the IRA
-93 anion resin caused a significant release of NO3-N from resins with no N
addition. Although the variation was large, the mixed bed resin MB 1 indic
ated a release of NH4-N, which supports results from long term in situ depl
oyments. A reduced adsorption of NO3-N was found on the IRA-93 anion resins
and the MB1 mixed bed resins that were dried prior to N addition while the
dry IR-120 cation resins adsorbed significantly less NH4-N than the contro
l resin. No effect of freezing and thawing efficiency was observed on resin
stability or N adsorption efficiency. Sufficient blanks that have been sub
jected to similar moisture changes are necessary in N limited systems with
low levels of available NH4-N and NO3-N.