Trigonal-bipyramidal anion [Ph2Cl3Sn](-) in the structure of N-[(diethylphosphoryl)methyl]-piperidinium diphenyltrichlorostannate(IV)

Authors
Yatsenko, AV Paseshnichenko, KA Petrosyan, VS Yashina, NS Grigoriev, EV Aslanov, LA
Citation
Av. Yatsenko et al., Trigonal-bipyramidal anion [Ph2Cl3Sn](-) in the structure of N-[(diethylphosphoryl)methyl]-piperidinium diphenyltrichlorostannate(IV), CROAT CHEM, 72(2-3), 1999, pp. 457-464
Citations number
17
Categorie Soggetti
Chemistry
Journal title
CROATICA CHEMICA ACTA
ISSN journal
00111643 → ACNP
Volume
72
Issue
2-3
Year of publication
1999
Pages
457 - 464
Database
ISI
SICI code
0011-1643(199909)72:2-3<457:TA[ITS>2.0.ZU;2-2
Abstract
Crystal structure of N-[(diethylphosphoryl)methyl]-piperidinium diphenyltri chlorostannate(IV), [C10H23NO3P](+) [C12H10Cl3Sn](-) has been determined, a = 11.416(2), b = 11.582(2), c = 12.491(2) Angstrom, alpha = 69.82(2), beta = 81.22(2), gamma = 60.73(2)degrees, space group P (1) over bar, 4493 refl ections, R(F)= 0.0271, wR(F-2)= 0.0712. The structure consists of isolated trigonal-bipyramidal anions and hydrogen-bonded dimers formed by cations. T he impact of secondary Sn...Cl interactions on the geometry of complex anio ns is discussed.