SEQUENCED REACTIONS WITH SAMARIUM(II) IODIDE - SEQUENTIAL NUCLEOPHILIC ACYL SUBSTITUTION KETYL OLEFIN COUPLING REACTIONS FOR THE PREPARATION OF OXYGEN HETEROCYCLES/

Authors
MOLANDER GA HARRIS CR
Citation
Ga. Molander et Cr. Harris, SEQUENCED REACTIONS WITH SAMARIUM(II) IODIDE - SEQUENTIAL NUCLEOPHILIC ACYL SUBSTITUTION KETYL OLEFIN COUPLING REACTIONS FOR THE PREPARATION OF OXYGEN HETEROCYCLES/, Journal of organic chemistry, 62(9), 1997, pp. 2944-2956
Citations number
84
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
62
Issue
9
Year of publication
1997
Pages
2944 - 2956
Database
ISI
SICI code
0022-3263(1997)62:9<2944:SRWSI->2.0.ZU;2-8
Abstract
Samarium(II) iodide has been employed to promote a sequential intramol ecular nucleophilic acyl substitution/intramolecular ketyl olefin coup ling cyclization sequence to provide bicyclic, tricyclic, and spiro-fu sed oxygen heterocycles in excellent yield and with high diastereosele ctivity.