Toasting changes both the quantity and the quality of the extractable subst
ances in oak wood of barrels used for the aging of fine wines and spirits.
Mastery and repeatability of toasting are vital in the production of qualit
y barrels to be used for aging wines and spirits. Toasted wood components,
which can be extracted by the wines or spirits during the aging process, ar
e normally analyzed by maceration in standard alcohol solutions at concentr
ations adapted to the various products and can be used to control the inten
sity of the wood toasting. These kinds of analyses are accurate but time-co
nsuming and need specialized laboratories. In this work, the feasibility of
monitoring barrel toasting levels using an electronic nose with a metal ox
ide odor sensor array (MOS) was studied. The results of oak toasting level
differentiation obtained via the MOS network were identical to those obtain
ed by analyzing extractable compounds in liquid or gas phase as described i
n a previous paper. The results presented in this work at the laboratory sc
ale could be used to implement a nondestructive monitoring system based on
the analysis of headspace of barrels under industrial conditions.