Inorganic esters of ethylene glycol as macrocyclic ligands

Authors
Schroeder, G Gierczyk, B Leska, B
Citation
G. Schroeder et al., Inorganic esters of ethylene glycol as macrocyclic ligands, J INCL P MA, 35(1), 1999, pp. 327-334
Citations number
6
Categorie Soggetti
Chemistry
Journal title
JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY
ISSN journal
13883127 → ACNP
Volume
35
Issue
1
Year of publication
1999
Pages
327 - 334
Database
ISI
SICI code
1388-3127(1999)35:1<327:IEOEGA>2.0.ZU;2-Y
Abstract
Six different inorganic esters of ethylene glycol: B(OR)(3), P(OR)(3), OS(O R)(2), OP(OR)(3), OPH(OR)(2) and As(OR)(3), where R = CH2CH2OCH3 were obtai ned. Their structures were studied by multinuclear NMR. These compounds can complex metal cations and behave like macrocyclic ligands. The influence o f metal cation complexation on spectra were investigated by H-1, C-13, O-17 , B-11, Li-7, Rb-87 and P-31 NMR.