When parchment and leather are subjected to humidity changes there are corr
esponding changes in temperature due to the gain and loss of water. This pa
per examines, refines and applies to parchment a thermal technique previous
ly used for the analysis of the condition of historical leather. The magnit
ude, duration and decay of the thermal response of modern and historical pa
rchments have been determined. The thermal response for historical parchmen
ts is different to those which are modern. Generally, relaxation times are
slower for rehydration when compared to dehydration. Historical parchments
are gradually changing from a collagen like structure to a more gelatin-lik
e structure.
No significant changes in thermal response was observed within an artificia
lly aged set of modern parchments using this technique. This suggests that
artificial ageing does not reproduce all of the changes found in historical
parchments. The thermal response and thermal decay half-life of leather is
much smaller than that of parchment on a mass per unit area basis.