An interpretation of the formation of alpha- and beta-form crystals in bulk syndiotactic polystyrene

Citation
Ws. Bu et al., An interpretation of the formation of alpha- and beta-form crystals in bulk syndiotactic polystyrene, MACROMOLEC, 32(21), 1999, pp. 7224-7225
Citations number
9
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
MACROMOLECULES
ISSN journal
00249297 → ACNP
Volume
32
Issue
21
Year of publication
1999
Pages
7224 - 7225
Database
ISI
SICI code
0024-9297(19991019)32:21<7224:AIOTFO>2.0.ZU;2-Q
Abstract
The crystallization of the alpha- and beta-form crystals of syndiotactic po lystyrene (sPS) is determined by the crystallization temperature. Being cry stallized at various temperatures from the melt, sPS forms the beta form cr ystal at high temperatures above about 230 degrees C, alpha form crystal at law temperatures below about 170 degrees C and a mixture of the alpha and beta form at intermediate temperatures.