The quantum confined Pockels effect has been observed in type-II ZnSe/BeTe
quantum well structures. In order to describe the in-plane optical anisotro
py induced by the electric held in type-II heterostructures, a theoretical
approach has been developed which is based on the representation of optical
matrix elements in the microscopical tight-binding model. It is shown that
polarized light spectroscopy allows one to obtain microscopic information
on interfaces in heterostructures, especially on the orientation of chemica
l bonds.