Mass transfer model for supercritical fluid extraction tests

Citation
Me. Al-jabari et Me. Weber, Mass transfer model for supercritical fluid extraction tests, SEP SCI TEC, 34(14), 1999, pp. 2853-2863
Citations number
11
Categorie Soggetti
Chemistry
Journal title
SEPARATION SCIENCE AND TECHNOLOGY
ISSN journal
01496395 → ACNP
Volume
34
Issue
14
Year of publication
1999
Pages
2853 - 2863
Database
ISI
SICI code
0149-6395(1999)34:14<2853:MTMFSF>2.0.ZU;2-C
Abstract
A mass transfer model using a linear equilibrium isotherm is presented for the static and dynamic stages of supercritical fluid extraction tests. In t he static stage the fraction extracted is a function of a dimensionless tim e and a dimensionless equilibrium parameter. In the dynamic stage the fract ion recovered is a function of a different dimensionless time, the same equ ilibrium parameter, and a dimensionless mass transfer parameter. Fitting th e model to experimental extraction curves showed that increasing the pressu re or density increases the equilibrium constant and decreases the overall mass transfer coefficient.