Substituted metal carbonyls: [{{(p-MeOC6H4)(2)Te}M(CO)(4)}](2) (M = Mn or Re) in the presence of an O-atom transfer reagent

Authors
Liu, X Gao, YC Su, ZX Wang, YY Shi, QZ
Citation
X. Liu et al., Substituted metal carbonyls: [{{(p-MeOC6H4)(2)Te}M(CO)(4)}](2) (M = Mn or Re) in the presence of an O-atom transfer reagent, TRANSIT MET, 24(6), 1999, pp. 666-668
Citations number
24
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
24
Issue
6
Year of publication
1999
Pages
666 - 668
Database
ISI
SICI code
0340-4285(1999)24:6<666:SMC[(=>2.0.ZU;2-G
Abstract
Two novel telluroether-disubstituted metal carbonyls, [(R2Te)M(CO)(4)](2) ( M = Mn or Re; R = p-MeOC6H4), were prepared from [M-2(CO)(10)] by an oxygen atom transfer. The axial CO is replaced by the telluroether when [M-2(CO)( 10)] reacts with a new kind of oxygen transfer reagent, R2TeO, under mild c onditions. The products were characterized by elemental analysis, i.r., H-1 - and C-13-n.m.r., and FAB-mass spectra. The configuration of the substitut ed carbonyl is unique, i.e. the 1, l'-diax isomer.