1 : 4 complexes of cobalt(II) azide with pyridine derivative ligands. X-ray crystal structure of trans-diazidotetrakis(4-benzoylpyridine) cobalt(II)

Authors
Goher, MAS Mautner, FA
Citation
Mas. Goher et Fa. Mautner, 1 : 4 complexes of cobalt(II) azide with pyridine derivative ligands. X-ray crystal structure of trans-diazidotetrakis(4-benzoylpyridine) cobalt(II), TRANSIT MET, 24(6), 1999, pp. 693-696
Citations number
25
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
TRANSITION METAL CHEMISTRY
ISSN journal
03404285 → ACNP
Volume
24
Issue
6
Year of publication
1999
Pages
693 - 696
Database
ISI
SICI code
0340-4285(1999)24:6<693:1:4COC>2.0.ZU;2-H
Abstract
A new series of CoL4(N-3)(2) complexes (L = 4-Et, 4-PhCO and 3-hydroxypyrid ine) has been prepared and characterized and their i.r. and electronic spec tra is reported and discussed. The structure of Co(4-benzoylpyridine)(4)(N- 3)(2), as determined by X-ray crystallography, consists of discrete monomer s molecules with a trans-six-coordinated cobalt(II) environment. The termin al azides are almost linear and asymmetric within the experimental error.