The paper reports the findings of four years of pilot-scale research on nit
rogen removal in fixed-bed biofilters fed on real raw municipal wastewater.
The plant was made of two fixed-bed biofilm reactors in series with an int
ermediate settling tank from which excess biomass from the first stage was
discharged. The first filter was used for carbon removal either with oxygen
or nitrates. The second filter was used for nitrification. The average nit
rification rate at 20 degrees C was 0.84 gNH(4)(+)-N m(-2)d(-1) with 5 mg 1
(-1) dissolved oxygen in the bulk liquid. Temperature dependence was calcul
ated (r(n) = r(n,20 degrees) 1,05(T-20)). The influent organic load strongl
y affected ammonia oxidation. If the organic loading exceeded 2.5 gCOD m(-2
) d(-1) nitrification rate was reduced by 50%. Denitrification was performe
d by recycling nitrates back from the second filter and by using sewage its
elf as carbon source. Denitrification rate showed to be strongly dependent
on temperature (r(d) = r(d.20 degrees) 1.11(T-20)) and on the recycle rate.
Hydrolysis of the colloidal COD fraction showed a similar dependence on bo
th temperature and recycle rate. Therefore, it has been concluded that the
hydrolysis of finely dispersed COD particles can be the limiting step of de
nitrification in the biofilter when real sewage is used as carbon source. (
C) 1999 IAWQ Published by Elsevier Science Ltd. All rights reserved.