1,5-anhydro-d-fructose: Regioselective acylation with fatty acids

Authors
Andersen, SM Lundt, I Marcussen, J Yu, SK
Citation
Sm. Andersen et al., 1,5-anhydro-d-fructose: Regioselective acylation with fatty acids, CARBOHY RES, 320(3-4), 1999, pp. 250-256
Citations number
22
Categorie Soggetti
Agricultural Chemistry","Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
CARBOHYDRATE RESEARCH
ISSN journal
00086215 → ACNP
Volume
320
Issue
3-4
Year of publication
1999
Pages
250 - 256
Database
ISI
SICI code
0008-6215(19990815)320:3-4<250:1RAWFA>2.0.ZU;2-0
Abstract
Regioselective acylation of 1,5-anhydro-D-fructose was performed with dodec anoic acid to give 1,5-anhydro-6-O-dodecanoyl-D-fructose, chemically in 50% yield and enzymatically in quantitative yield. Quantitative conversions we re also obtained using hexadecanoic and octadecanoic acids as acyl donors. (C) 1999 Elsevier Science Ltd. All rights reserved.