Self-assembled monolayers of non-heme diiron(III) model complexes on Au(111) electrode: Synthesis and proton-coupled redox behavior in water

Authors
Inomata, T Abe, M Kondo, T Umakoshi, K Uosaki, K Sasaki, Y
Citation
T. Inomata et al., Self-assembled monolayers of non-heme diiron(III) model complexes on Au(111) electrode: Synthesis and proton-coupled redox behavior in water, CHEM LETT, (10), 1999, pp. 1097-1098
Citations number
20
Categorie Soggetti
Chemistry
Journal title
CHEMISTRY LETTERS
ISSN journal
03667022 → ACNP
Issue
10
Year of publication
1999
Pages
1097 - 1098
Database
ISI
SICI code
0366-7022(199910):10<1097:SMONDM>2.0.ZU;2-2
Abstract
Self-assembled monolayers (SAMs) of non-heme diiron(III) biomimetic complex es have been prepared on Au(lll) electrode surfaces to explore redox proper ties of diiron centers in aqueous solution in a wide pH range. The diiron(I II) SAMs exhibited the proton-coupled electron-transfer reaction (1H(+)/1e( -)) in water.