High spin states in neutron-rich odd-N Ba-145 nucleus have been investigate
d from study of prompt gamma-rays in spontaneous fission of Cf-252. The alt
ernating parity bends are identified indicating octupole deformation with s
implex quantum number s = -i. The ground state band shows signature splitti
ng and inversion at low spin. These collective band structures exhibit the
competition and co-existence between symmetric and asymmetric shapes.