Synthesis and X-ray crystallographic structures of dichloronickel(II) and -palladium(II) complexes containing the biphenyl diamine ligand 6-(2-dimethylaminoethyl)-6,7-dihydro-5-H-dibenz[c,e]azepin

Authors
Marchetti, F Tanturli, R Pertici, P Rosini, C
Citation
F. Marchetti et al., Synthesis and X-ray crystallographic structures of dichloronickel(II) and -palladium(II) complexes containing the biphenyl diamine ligand 6-(2-dimethylaminoethyl)-6,7-dihydro-5-H-dibenz[c,e]azepin, INORG CHIM, 294(1), 1999, pp. 28-34
Citations number
34
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
294
Issue
1
Year of publication
1999
Pages
28 - 34
Database
ISI
SICI code
0020-1693(19991102)294:1<28:SAXCSO>2.0.ZU;2-8
Abstract
The diamine N <^> N (N <^> N = 6-(2-dimethylaminoethyl)-6,7-dihydro-5-H-dib enz[c,e]azepin (1)) has been prepared and characterised. It reacts with nic kel(II) chloride and bis(benzonitrile)dichloropalladium giving the correspo nding complexes MCl2(N <^> N) (M = Ni, 6; Pd, 7) whose crystal structures h ave been determined. The nickel coordination in complex 6 is distorted tetr ahedral, whereas the palladium coordination in complex 7 is square planar. (C) 1999 Elsevier Science S.A. All rights reserved.