[Cd-2(4,4 '-bipy)(2)(H2O)(3)(SO4)(2)]center dot 3H(2)O: a novel three-dimensional coordination polymer with nonlinear optical properties

Authors
Huang, SPD Xiong, RG Han, JD Weiner, BR
Citation
Spd. Huang et al., [Cd-2(4,4 '-bipy)(2)(H2O)(3)(SO4)(2)]center dot 3H(2)O: a novel three-dimensional coordination polymer with nonlinear optical properties, INORG CHIM, 294(1), 1999, pp. 95-98
Citations number
29
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
294
Issue
1
Year of publication
1999
Pages
95 - 98
Database
ISI
SICI code
0020-1693(19991102)294:1<95:['D3AN>2.0.ZU;2-5
Abstract
The three-dimensional coordination polymer [Cd-2(4,4'-bipy)(2)(H2O)(3)(SO4) (2)]. 3H(2)O (1) was synthesized by the hydrothermal reaction of 4,4'-bipyr idine with CdSO4. 8/3H(2)O in 1:1 mole ratio in a sealed tube at 120 degree s C. The compound was characterized by FT-IR, diffuse reflectance UV-Vis, X -ray powder diffraction and single crystal X-ray analysis. The structure fe atures three-dimensional, interwoven networks. Semiquantitative Kurtz-Perry powder measurements showed that 1 possesses a second-order harmonic genera tion efficiency of ca. 27% of potasium dihydrogen phosphate. (C) 1999 Elsev ier Science S.A. All rights reserved.