Coordination mode of dihydroxybenzoic acids in oxorhenium(V) complexes

Authors
Bandoli, G Dolmella, A Gerber, TIA Perils, J du Preez, JGH
Citation
G. Bandoli et al., Coordination mode of dihydroxybenzoic acids in oxorhenium(V) complexes, INORG CHIM, 294(1), 1999, pp. 114-118
Citations number
18
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
INORGANICA CHIMICA ACTA
ISSN journal
00201693 → ACNP
Volume
294
Issue
1
Year of publication
1999
Pages
114 - 118
Database
ISI
SICI code
0020-1693(19991102)294:1<114:CMODAI>2.0.ZU;2-J
Abstract
Trans-ReOCl3(PPh3)(2) reacts with 2,3- and 2,6-dihydroxybenzoic acid (H(2)d hb) in an equimolar ratio in benzene to give the products [ReOCl(2,3-dhb)(P Ph3)(2)] (1) and [ReOCl(2,6-dhb)(PPh3)(2)] (2), respectively. Elemental ana lysis, infrared, NMR and X-ray crystallographic results indicate that the l igand 2,3-dhb coordinates via the catecholato mode to the metal centre in 1 , but 2,6-dhb functions as a salicylato-type chelate in 2. (C) 1999 Elsevie r Science S.A. All rights reserved.