M. Kitayama et al., Control of beta-Si3N4 crystal morphology and its mechanism (Part 1) - Effect of SiO2 and Y2O3 ratio, J CERAM S J, 107(10), 1999, pp. 930-934
The effect of Y2O3/SiO2 ratio on grain growth of Si3N4 was systematically i
nvestigated using the "seed" fabrication method. The aspect ratio of beta-S
i3N4 crystals heat-treated with an additive composition of Y2O3 : SiO2 = 1
: 2 was found to be much smaller than that of Y2O3 : SiO2 = 2 : 1. It was c
onfirmed that this was due to the difference in solubility of Si3N4 caused
by the change of Y2O3/SiO2 ratio of the liquid phase. The number of a-cryst
als originally contained in the raw Si3N4 powder changed very little in the
Y2O3 : SiO2 = 1 : 2 composition, while it significantly decreased in the Y
2O3 : SiO2 = 2 : 1 composition, which resulted in a considerable difference
in aspect ratio. A mechanism for this enhanced solubility of Si3N4 in the
liquid phase with high Y2O3/SiO2 ratio was proposed.