J. Pola et al., Infrared laser-induced decomposition of tert-butylsilane for chemical vapour deposition of Si/C/H phases, MAIN GR MET, 22(9), 1999, pp. 545-552
TEA CO2 laser induced decomposition of tert-butylsilane is controlled by el
imination of isobutene and affords solid Si/C/H films whose H-content is de
pendent on the laser fluence. The process of the chemical vapour deposition
of Si/C/H phases is a unique from the viewpoint that depending on the irra
diation conditions different major component of the solid films (either ele
mental silicon or-silicon carbide) can be obtained from the only single pre
cursor.