An on-line purification system for a large-scale low-background liquid scin
tillation detector has been tested with the 5-ton liquid scintillation dete
ctor, the Counting Test Facility at Gran Sasso. Counter-current water extra
ction removes polar and charged impurities such as ions and metal salts. Va
cuum distillation of the entire scintillator has been applied to remove bot
h radioactive impurities and chemical impurities that affect the optical pr
operties of the scintillator. Filtration with a 0.05 mu m particulate filte
r removed suspended dust particles that may contain U, Th and K. Nitrogen s
tripping was employed to remove dissolved water and noble gases (e.g. Kr-85
) from the scintillator. The system has effectively reduced the internal ba
ck in the 5 ton liquid scintillation detector from 470+/-90 events/d to the
detection limit of the detector (+/-45 events/d) in the energy window 250<
E<800 keV.