Application of phosphaalkenes and phosphaalkynes in organophosphorus chemistry, new results

Authors
Denis, JM Benie, A Gaumont, AC Pilard, JF
Citation
Jm. Denis et al., Application of phosphaalkenes and phosphaalkynes in organophosphorus chemistry, new results, PHOSPHOR SU, 146, 1999, pp. 97-100
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
146
Year of publication
1999
Pages
97 - 100
Database
ISI
SICI code
1042-6507(1999)146:<97:AOPAPI>2.0.ZU;2-M
Abstract
Free phosphaalkenes are prepared by stereocontrolled rearrangement of vinyl phosphines and beta-elimination of alpha,alpha'-dichloroalkylphosphines. Sy nthetic potential is evaluated in inter- and intramolecular [4+2] cycloaddi tions.