Application of phosphaalkenes and phosphaalkynes in organophosphorus chemistry, new results

Citation
Jm. Denis et al., Application of phosphaalkenes and phosphaalkynes in organophosphorus chemistry, new results, PHOSPHOR SU, 146, 1999, pp. 97-100
Citations number
14
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
146
Year of publication
1999
Pages
97 - 100
Database
ISI
SICI code
1042-6507(1999)146:<97:AOPAPI>2.0.ZU;2-M
Abstract
Free phosphaalkenes are prepared by stereocontrolled rearrangement of vinyl phosphines and beta-elimination of alpha,alpha'-dichloroalkylphosphines. Sy nthetic potential is evaluated in inter- and intramolecular [4+2] cycloaddi tions.