Reported in this paper are the separation characteristics and transport mec
hanisms of membranes formed from poly[bis(phenoxy)phosphazene] based polyme
rs. Separations of industrial interest include water purification, gas sepa
rations, liquid state organic-water and organic-organic separations. Many o
f these environments are chemically aggressive which often leads to the fai
lure of many standard organic-based membrane materials and the polyphosphaz
enes have been observed to effectively operate in such environments. In thi
s paper, we will develop an argument that shows the value of custom tailori
ng these membrane materials to fit the specific application of water purifi
cation.