New vanadium phosphonate clusters and coordination polymers

Authors
Meisel, M Wulff-Molder, D
Citation
M. Meisel et D. Wulff-molder, New vanadium phosphonate clusters and coordination polymers, PHOSPHOR SU, 146, 1999, pp. 231-234
Citations number
6
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
146
Year of publication
1999
Pages
231 - 234
Database
ISI
SICI code
1042-6507(1999)146:<231:NVPCAC>2.0.ZU;2-V
Abstract
The solvothermal synthesis of vanadyl phosphonates has been studied under d ifferent conditions. Starting from dichlorovanadate, M[(VO2Cl2)-O-V] (M = P Ph4, MePPh3), or decavanadate and phosphonic acids, RPO3H2 (R = Me, tBu, Ph ), the formation of oxovanadium clusters under the directing influence of t emplates as well as of different solvents has been investigated. It is also shown that the cation M influences the formed oxovanadium structures as we ll as the rests in the phosphonic acids because of their different steric b ehaviour.