New carbon-phosphorus macrocycles

Authors
Mathey, F Mercier, F Le Floch, P
Citation
F. Mathey et al., New carbon-phosphorus macrocycles, PHOSPHOR SU, 146, 1999, pp. 251-256
Citations number
12
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
146
Year of publication
1999
Pages
251 - 256
Database
ISI
SICI code
1042-6507(1999)146:<251:NCM>2.0.ZU;2-Z
Abstract
The synthesis of several phosphole and phosphinine-based macrocycles is des cribed. The first ones are flexible as a result of the low inversion barrie r of phosphorus. The mixture of isomers can be directly used in coordinatio n chemistry. The second ones are not plagued by conformational problems and display strong pi-acceptor properties.