Arbuzov reaction in the series of halogenocyclenes: New synthetical and mechanistical variants

Citation
Ra. Cherkasov et al., Arbuzov reaction in the series of halogenocyclenes: New synthetical and mechanistical variants, PHOSPHOR SU, 146, 1999, pp. 333-336
Citations number
6
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
146
Year of publication
1999
Pages
333 - 336
Database
ISI
SICI code
1042-6507(1999)146:<333:ARITSO>2.0.ZU;2-T
Abstract
A new method of synthesis of phosphorylated furanones on the basis of trico ordinated phosphorus derivatives reaction with mucochloric acid and some of its derivatives is elaborated. The kinetic investigation of the reaction o f phosphites (1, R = Me, Pt, Pr, Bu, Ph) with mucochloric acid allowed to e stablish the reaction mechanism including competitive elimination of RCl or HCl from the obtaining intermediate. The ratio of these two possible react ion ways depends on the nature of substituents at phosphorus.