Ra. Cherkasov et al., Arbuzov reaction in the series of halogenocyclenes: New synthetical and mechanistical variants, PHOSPHOR SU, 146, 1999, pp. 333-336
Citations number
6
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
A new method of synthesis of phosphorylated furanones on the basis of trico
ordinated phosphorus derivatives reaction with mucochloric acid and some of
its derivatives is elaborated. The kinetic investigation of the reaction o
f phosphites (1, R = Me, Pt, Pr, Bu, Ph) with mucochloric acid allowed to e
stablish the reaction mechanism including competitive elimination of RCl or
HCl from the obtaining intermediate. The ratio of these two possible react
ion ways depends on the nature of substituents at phosphorus.