P-zwitterions from trialkylphosphines and 2-cyanoacrylates

Citation
Yg. Gololobov et al., P-zwitterions from trialkylphosphines and 2-cyanoacrylates, PHOSPHOR SU, 146, 1999, pp. 355-358
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
146
Year of publication
1999
Pages
355 - 358
Database
ISI
SICI code
1042-6507(1999)146:<355:PFTA2>2.0.ZU;2-B
Abstract
The recent developments in the chemistry of P-zwitterions 2 are discussed. They include unusual reactions of 2 with HgCl2, ArN3, TosNCO and Alk(Ar)NCX (X=O,S). The insertion reactions of alkyiso(thio)cyanates into C-C bond ar e considered. A novel type of the intramolecular electrophilic rearrangemen ts is described.