Phosphonium diylides in organic synthesis

Citation
M. Taillefer et al., Phosphonium diylides in organic synthesis, PHOSPHOR SU, 146, 1999, pp. 401-404
Citations number
4
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
146
Year of publication
1999
Pages
401 - 404
Database
ISI
SICI code
1042-6507(1999)146:<401:PDIOS>2.0.ZU;2-5
Abstract
Phosphonium diylides afford a general synthetic method for numerous alpha,b eta-unsaturated functions, the double bond being di- or trisubstituted. The diamino-phosphonium diylides, obtained in the case of stabilized ones by a new variation of die Staudinger reaction, are also interesting tools in sy nthesis because they allow access to, for example ketenimines, phosphorus g uanidines or triazaphosphinimines.