Novel routes to 1,2-diphosphete and 1,2,4-triphospholyl pi-complexes

Authors
Elvers, A Heinemann, F Kummer, S Wrackmeyer, B Zeller, M Zenneck, U
Citation
A. Elvers et al., Novel routes to 1,2-diphosphete and 1,2,4-triphospholyl pi-complexes, PHOSPHOR SU, 146, 1999, pp. 725-728
Citations number
7
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS
ISSN journal
10426507 → ACNP
Volume
146
Year of publication
1999
Pages
725 - 728
Database
ISI
SICI code
1042-6507(1999)146:<725:NRT1A1>2.0.ZU;2-P
Abstract
New specific routes to 1,2-diphosphete-, 1,2,4-triphosphol-, and 1,2,4-trip hospholyl-pi-complexes are reported, which are based on dichloro-l,2-diphos phetene and I-stannyl-l,2,4-triphosphol as the heterocyclic educts. Details are given for Sn, Mn, Fe, and Co complexes. ESR-data of paramagnetic 1,2,4 -triphospholyl sandwich complexes of Co and Mn proof the absence of degener ate SOMOs in these cases.