Benzylisopropyldithiocarbamate complexes of nickel with triphenylphosphinein the coordination sphere

Authors
Pastorek, R Kamenicek, J Travnicek, Z Husarek, J Duffy, N
Citation
R. Pastorek et al., Benzylisopropyldithiocarbamate complexes of nickel with triphenylphosphinein the coordination sphere, POLYHEDRON, 18(22), 1999, pp. 2879-2883
Citations number
19
Categorie Soggetti
Inorganic & Nuclear Chemistry
Journal title
POLYHEDRON
ISSN journal
02775387 → ACNP
Volume
18
Issue
22
Year of publication
1999
Pages
2879 - 2883
Database
ISI
SICI code
0277-5387(1999)18:22<2879:BCONWT>2.0.ZU;2-1
Abstract
Nickel(II) benzylisopropyldithiocarbamate complexes of the composition [Ni( bz(i)Prdtc)(2)], [NiCl(bz(i)Prdtc)(PPh3)]. CHCl3 and [NiX(bz(i)Prdtc)(PPh3) ] (X=Cl, Br, I, NCS; bz=C7H7, Pr-i=C3H7, dtc=S2CN-, PPh3 = triphenylphosphi ne) have been synthesized. The complexes have been characterized by element al analyses, IR and electronic spectroscopies, thermal analysis, magnetoche mical and conductivity measurements. A single crystal X-ray analysis of the [NiCl(bz(i)Prdtc)(PPh3)]. CHCl3, [NiBr(bz(i)Prdtc)(PPh3)] and [NiI(bz(i)Pr dtc)(PPh3)] confirms four-coordinated nickel in a distorted square-planar a rrangement with the NiS2PX chromophore. (C) 1999 Elsevier Science Ltd. All rights reserved.