Static and dynamic light scattering from polystyrene/cyclohexane/toluene solutions

Citation
A. Negadi et al., Static and dynamic light scattering from polystyrene/cyclohexane/toluene solutions, POLYM BULL, 43(2-3), 1999, pp. 261-267
Citations number
19
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
POLYMER BULLETIN
ISSN journal
01700839 → ACNP
Volume
43
Issue
2-3
Year of publication
1999
Pages
261 - 267
Database
ISI
SICI code
0170-0839(199909/10)43:2-3<261:SADLSF>2.0.ZU;2-M
Abstract
Static and dynamic light scattering data from polystyrene in cyclohexane an d toluene mixed solvent are reported. It is found from the Zimm plot analys is of the static data that if the subtraction of solvent signal is made pro perly then, the results are consistent with those in toluene indicating a p referential adsorption of the good solvent. Contin analysis of the dynamic data yields two modes unlike the dynamics of polystyrene in single solvent solutions which exhibit a single mode at all polymer concentrations covered here. A possible interpretation of the fast and slow modes is given.