A Bayesian methodology is developed for groundwater leak detection at
waste disposal sites. The method requires specification of the prior p
robability of a leak at the facility and updates this probability base
d on the proportion of constituent observations above a threshold valu
e (e.g., the analytical detection limit) in the monitoring versus the
background samples. The information content of a chemical measurement
is characterized by the probability of occurrence of elevated concentr
ations of the chemical in a monitoring well, given the presence or abs
ence of a facility leak. The evidence from multiple constituents is co
mbined, assuming independence of errors, into a single aggregate estim
ate for the posterior probability of a leak. The procedure allows expe
rt knowledge on site conditions and chemical behavior in the groundwat
er to be systematically incorporated in the regulatory evaluation of l
eak detection monitoring data. Applications using hypothetical and act
ual monitoring data from a hazardous waste facility demonstrate the pr
ocedure and highlight needs for further research.