Synthesis of hydroxycedranone and aminohydroxycedrane

Authors
Song, YL Wang, QR Ding, ZB Tao, FG
Citation
Yl. Song et al., Synthesis of hydroxycedranone and aminohydroxycedrane, SYN COMMUN, 29(23), 1999, pp. 4171-4178
Citations number
17
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
29
Issue
23
Year of publication
1999
Pages
4171 - 4178
Database
ISI
SICI code
0039-7911(1999)29:23<4171:SOHAA>2.0.ZU;2-1
Abstract
Two optically pure derivatives of alpha-cedrene - (1R,2R,5S,7R,8R)8-hydroxy -9-cedranone 2 and (1R,2R,5S,7R,8R,9S)-9-amino-8-hydroxycedrane 4 were prep ared conveniently. An X-ray structural analysis of 2 was performed indicati ng that the hydroxycedranone exists as dimer due to one hydrogen bond in so lid state.