Reaction of N-(benzyloxycarbonyl)aminobenzylphosphonous acid with ethyl orthoformate

Citation
A. Stano et al., Reaction of N-(benzyloxycarbonyl)aminobenzylphosphonous acid with ethyl orthoformate, SYN COMMUN, 29(23), 1999, pp. 4269-4277
Citations number
28
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
SYNTHETIC COMMUNICATIONS
ISSN journal
00397911 → ACNP
Volume
29
Issue
23
Year of publication
1999
Pages
4269 - 4277
Database
ISI
SICI code
0039-7911(1999)29:23<4269:RONAWE>2.0.ZU;2-C
Abstract
Reaction of N-(benzyloxycarbonyl)aminobenzylphosphonous acid with ethyl ort hoformate afforded two major products diethyl N-(benzyloxycarbonyl)aminoben zylphosphinite and ethyl (diethoxymethyl)[N-(benzyloxy-carbonyl)aminobenzyl ]phosphinate, a product of addition of phosphonous acid to orthoformate.