Disaccharide synthesis on a soluble hyperbranched polymer

Authors
Kantchev, AB Parquette, JR
Citation
Ab. Kantchev et Jr. Parquette, Disaccharide synthesis on a soluble hyperbranched polymer, TETRAHEDR L, 40(46), 1999, pp. 8049-8053
Citations number
22
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
46
Year of publication
1999
Pages
8049 - 8053
Database
ISI
SICI code
0040-4039(19991112)40:46<8049:DSOASH>2.0.ZU;2-F
Abstract
A hyperbranched star polymer was employed as a soluble support for disaccha ride synthesis as a practical alternative to a dendrimer support. The large number of terminal groups present on the support permit very high loading levels to be possible. Polymer bound intermediates could be directly analyz ed by MALDI-TOF mass spectrometry due to the presence of a photolabile link er that is cleaved by the MALDI-TOF laser. (C) 1999 Elsevier Science Ltd. A ll rights reserved.