First synthesis of alpha-fluorinated cyclopropylphosphonates using magnesium electrochemical activation

Authors
Goumain, S Jubault, P Feasson, C Quirion, JC
Citation
S. Goumain et al., First synthesis of alpha-fluorinated cyclopropylphosphonates using magnesium electrochemical activation, TETRAHEDR L, 40(46), 1999, pp. 8099-8101
Citations number
15
Categorie Soggetti
Chemistry & Analysis","Organic Chemistry/Polymer Science
Journal title
TETRAHEDRON LETTERS
ISSN journal
00404039 → ACNP
Volume
40
Issue
46
Year of publication
1999
Pages
8099 - 8101
Database
ISI
SICI code
0040-4039(19991112)40:46<8099:FSOACU>2.0.ZU;2-C
Abstract
The synthesis of alpha-fluorinated cyclopropylphosphonates is efficiently a chieved for the first time by electroreduction of diisopropyl dibromofluoro methylphosphonate in the presence of Michael accepters in a one-compartment cell equipped with a magnesium sacrificial anode. (C) 1999 Elsevier Scienc e Ltd. All rights reserved.