It was established that the physical modification of poly(phenylquinoxaline
) through solution can be achieved by optimizing the composition of a mixed
solvent or by introducing small amounts of a second polymer, for example,
polycarbonate. The latter method yields transparent films; however, as evid
enced by dielectric spectrometry, the resulting composition is two-phase. O
n the basis of calorimetry and viscometry data, it is suggested that the en
hanced strength of films made of modified poly(phenylquinoxaline) is explai
ned by the cosolubility effect when the polymer is modified according to th
e first method, while in the second case, this phenomenon is attributed to
appearance of interpolymer interactions.