Modification of poly(phenylquinoxaline) through solution

Citation
Te. Knyazeva et al., Modification of poly(phenylquinoxaline) through solution, VYSO SOED, 41(7), 1999, pp. 1191-1194
Citations number
11
Categorie Soggetti
Organic Chemistry/Polymer Science
Journal title
VYSOKOMOLEKULYARNYE SOEDINENIYA SERIYA A & SERIYA B
ISSN journal
05075475 → ACNP
Volume
41
Issue
7
Year of publication
1999
Pages
1191 - 1194
Database
ISI
SICI code
0507-5475(199907)41:7<1191:MOPTS>2.0.ZU;2-R
Abstract
It was established that the physical modification of poly(phenylquinoxaline ) through solution can be achieved by optimizing the composition of a mixed solvent or by introducing small amounts of a second polymer, for example, polycarbonate. The latter method yields transparent films; however, as evid enced by dielectric spectrometry, the resulting composition is two-phase. O n the basis of calorimetry and viscometry data, it is suggested that the en hanced strength of films made of modified poly(phenylquinoxaline) is explai ned by the cosolubility effect when the polymer is modified according to th e first method, while in the second case, this phenomenon is attributed to appearance of interpolymer interactions.