A quantity has been introduced, whose dependence on the composition along t
he branches of the solubility isotherms of ternary systems consisting of tw
o salts with a common ion and water exhibits breaks, which can be explained
by the introduction of a previously unobserved configuration of the ternar
y saturated solution. In the respective region, a saturated solution in a t
ernary system may undergo second-order phase transitions to achieve specifi
c configurations that are not derived from the structure of the binary satu
rated solution of the particular solute. It is assumed that further study o
f this phenomenon could contribute to a better understanding of the process
es occurring in concentrated electrolyte solutions.