A contribution to the study of ternary saturated electrolyte solutions

Citation
J. Eysseltova et M. Ebert, A contribution to the study of ternary saturated electrolyte solutions, Z NATURFO A, 54(8-9), 1999, pp. 485-487
Citations number
9
Categorie Soggetti
Physical Chemistry/Chemical Physics
Journal title
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION A-A JOURNAL OF PHYSICAL SCIENCES
ISSN journal
09320784 → ACNP
Volume
54
Issue
8-9
Year of publication
1999
Pages
485 - 487
Database
ISI
SICI code
0932-0784(199908/09)54:8-9<485:ACTTSO>2.0.ZU;2-3
Abstract
A quantity has been introduced, whose dependence on the composition along t he branches of the solubility isotherms of ternary systems consisting of tw o salts with a common ion and water exhibits breaks, which can be explained by the introduction of a previously unobserved configuration of the ternar y saturated solution. In the respective region, a saturated solution in a t ernary system may undergo second-order phase transitions to achieve specifi c configurations that are not derived from the structure of the binary satu rated solution of the particular solute. It is assumed that further study o f this phenomenon could contribute to a better understanding of the process es occurring in concentrated electrolyte solutions.