Solubility of biphenyl in organic nonelectrolyte solvents. Comparison of observed versus predicted values based upon Mobile Order theory

Citation
Km. De Fina et al., Solubility of biphenyl in organic nonelectrolyte solvents. Comparison of observed versus predicted values based upon Mobile Order theory, CAN J CHEM, 77(10), 1999, pp. 1589-1593
Citations number
36
Categorie Soggetti
Chemistry
Journal title
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
ISSN journal
00084042 → ACNP
Volume
77
Issue
10
Year of publication
1999
Pages
1589 - 1593
Database
ISI
SICI code
0008-4042(199910)77:10<1589:SOBION>2.0.ZU;2-R
Abstract
Experimental solubilities are reported at 25.0 degrees C for biphenyl disso lved in 26 different alkane, dialkyl ether, and alcohol solvents. Results o f these measurements, combined with previously published biphenyl solubilit y data, are used to test the applications and limitations of expressions de rived from Mobile Order theory. For the 40 solvents for which predictions c ould be made computations show that Mobile Order theory does provide fairly reasonable estimates of the saturation mole fraction solubilities. Average absolute deviation between predicted and observed values is 13.0%.