Km. De Fina et al., Solubility of biphenyl in organic nonelectrolyte solvents. Comparison of observed versus predicted values based upon Mobile Order theory, CAN J CHEM, 77(10), 1999, pp. 1589-1593
Citations number
36
Categorie Soggetti
Chemistry
Journal title
CANADIAN JOURNAL OF CHEMISTRY-REVUE CANADIENNE DE CHIMIE
Experimental solubilities are reported at 25.0 degrees C for biphenyl disso
lved in 26 different alkane, dialkyl ether, and alcohol solvents. Results o
f these measurements, combined with previously published biphenyl solubilit
y data, are used to test the applications and limitations of expressions de
rived from Mobile Order theory. For the 40 solvents for which predictions c
ould be made computations show that Mobile Order theory does provide fairly
reasonable estimates of the saturation mole fraction solubilities. Average
absolute deviation between predicted and observed values is 13.0%.