Stepwise assembly of a polyoxovanadate from mononuclear units in an organic solvent: carboxylate-stabilised fragments in the conversion of [VOCl4](2-) to [V15O36](5-)

Authors
Karet, GB Sun, ZM Streib, WE Bollinger, JC Henderickson, DN Christou, G
Citation
Gb. Karet et al., Stepwise assembly of a polyoxovanadate from mononuclear units in an organic solvent: carboxylate-stabilised fragments in the conversion of [VOCl4](2-) to [V15O36](5-), CHEM COMMUN, (22), 1999, pp. 2249-2250
Citations number
15
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
22
Year of publication
1999
Pages
2249 - 2250
Database
ISI
SICI code
1359-7345(1999):22<2249:SAOAPF>2.0.ZU;2-U
Abstract
The [VOCl4](2-)/AgOAc reaction system in MeCN gives [V5O9Cl(OAc)(4)](2-), [ V9O19(OAc)(5)](3-) and [V15O36](5-) for reagent ratios of 1:2, 1:3 and 1:4, respectively: the V-5 and V-9 cores are fragments of the V-15 core, sugges ting the V-5 and V-9 units are carboxylate-stabilised intermediates in the assembly of the V-15 polyoxovanadate.