A bimodal dithiadiazolyl diradical: crystal structure and magnetic properties of the 2,2 '-dimethylbiphenylene bridged derivative

Authors
Barclay, TM Cordes, AW George, NA Haddon, RC Itkis, ME Oakley, RT
Citation
Tm. Barclay et al., A bimodal dithiadiazolyl diradical: crystal structure and magnetic properties of the 2,2 '-dimethylbiphenylene bridged derivative, CHEM COMMUN, (22), 1999, pp. 2269-2270
Citations number
20
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
22
Year of publication
1999
Pages
2269 - 2270
Database
ISI
SICI code
1359-7345(1999):22<2269:ABDDCS>2.0.ZU;2-F
Abstract
The two termini of the torsionally strained dithiadiazolyl diradical S2N2C- C6H3Me-MeC6H3-CN2S2 3 possess different solid state structural environments ; the bulk magnetic susceptibility of 3 is interpreted in terms of the dist inct properties of the two radical centres.