Dioxygen-copper reactivity at trinuclear centers: formation of hexanuclearand mixed-valent adducts

Authors
Karlin, KD Gan, QF Tyeklar, Z
Citation
Kd. Karlin et al., Dioxygen-copper reactivity at trinuclear centers: formation of hexanuclearand mixed-valent adducts, CHEM COMMUN, (22), 1999, pp. 2295-2296
Citations number
21
Categorie Soggetti
Chemistry
Journal title
CHEMICAL COMMUNICATIONS
ISSN journal
13597345 → ACNP
Issue
22
Year of publication
1999
Pages
2295 - 2296
Database
ISI
SICI code
1359-7345(1999):22<2295:DRATCF>2.0.ZU;2-R
Abstract
New copper(I) complexes [Cu-3(I)(mesO(-))](2+) (3) and [Cu-3(I)- (mesOH)](3 +) (4) have been generated from a phenol-containing trinucleating ligand, m esOH; reactions with O-2 reflect the unsymmetrical ligand environment, and lead to peroxo and/or hydroperoxo cluster complexes, including those with m ixed-valent copper ion centers.